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Study of the synergistic influence of zwitterionic interactions and graphene oxide on water diffusion mechanism and mechanical properties in hybrid hydrogel network. | LitMetric

Study of the synergistic influence of zwitterionic interactions and graphene oxide on water diffusion mechanism and mechanical properties in hybrid hydrogel network.

Chemosphere

College of Materials Science and Engineering, Shenzhen Key Laboratory of Polymer Science and Technology, Guangdong Research Center for Interfacial Engineering of Functional Materials, Shenzhen University, Shenzhen, 518055, PR China. Electronic address:

Published: February 2023

AI Article Synopsis

  • Researchers created hybrid hydrogels using n-isopropylacrylamide, zwitterionic comonomers, and graphene oxide to explore their physical and mechanical traits.
  • Variations in composition significantly affected the swelling properties of the hydrogels, showing a distinct two-step swelling pattern in zwitterion-containing gels and a strong covalent network as indicated by low phase angles.
  • Mechanical testing revealed that hydrogels with higher zwitterion and graphene oxide content performed better under stress, with brittle failure occurring at certain elongation strains, while higher graphene oxide also enhanced performance during compression.

Article Abstract

Hybrid hydrogels based on n-isopropylacrylamide, zwitterionic comonomer, and graphene oxide were synthesized to study their physical and mechanical properties. The compositional variation largely influenced the swelling characteristics of the hybrid hydrogels compared to mechanical properties, i.e., elongation and compression. Additionally, Rheometric swelling measurements on the swollen hydrogels were performed until they reached equilibrium showed a very low phase angle δ indicating strong covalent network, which intrun increases with increasing content of zwitterions and GO. Swelling kinetics were studied and found to follow Fickian dynamics, albeit zwitterion-containing gels showed a peculiar 2-step swelling pattern. Interestingly, differences in the swelling mechanism are also clear for the hydrogels with 2D GO (Graphene oxide) nano-fillers from its 1D nano-filler CNTs (Carbon nanotubes). In elongation, the samples break in a brittle fashion at Hencky strains ε around 0.4-0.65 with the maximum stress being observed for samples with high Zw-content and 0.2% GO, which can be explained by the stress-rising properties of sharp edges of GO. In contrast, the data in compression profits from higher GO-contents as crack growth is less important in this deformation mode. This work will contribute to future composite gel applications.

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Source
http://dx.doi.org/10.1016/j.chemosphere.2022.137710DOI Listing

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