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| http://dx.doi.org/10.1021/acscentsci.2c01438 | DOI Listing |
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The Somogyi hypothesis: a parallelism with Michael Somogyi's life.
Hormones (Athens)
December 2024
Department of Endocrinology and Nutrition, Hospital Universitario Central de Asturias/University of Oviedo, Oviedo, Spain.
Michael Somogyi (Somogyi Mihály, 1883-1971) was a Hungarian biochemist who developed his scientific career in Europe and, primarily, the United States. He gave the name to the eponymous Somogyi effect or Somogyi hypothesis (in short, rebound hyperglycemia after insulin-induced hypoglycemia, particularly nocturnal), which was an axiom in the treatment of diabetes for decades. Although it is currently debated whether the Somogyi hypothesis is a real or relevant phenomenon in patients with diabetes, Somogyi's other significant career achievements are often overlooked.
View Article and Find Full Text PDFMolecular Polaritons for Chemistry, Photonics and Quantum Technologies.
Chem Rev
March 2024
Department of Chemistry and Biochemistry, University of California, San Diego, California 92126, United States.
Molecular polaritons are quasiparticles resulting from the hybridization between molecular and photonic modes. These composite entities, bearing characteristics inherited from both constituents, exhibit modified energy levels and wave functions, thereby capturing the attention of chemists in the past decade. The potential to modify chemical reactions has spurred many investigations, alongside efforts to enhance and manipulate optical responses for photonic and quantum applications.
View Article and Find Full Text PDFThe Role of Artificial Intelligence for Providing Scientific Content for Laboratory Medicine.
J Appl Lab Med
March 2024
Department of Pathology, University of Maryland, Baltimore, MD, United States.
Background: Artificial intelligence (AI) promises to become an important tool in the practice of laboratory medicine. AI programs are available online that can provide concise medical and laboratory information within seconds after a question is submitted.
Methods: We posed the following contemporary and relevant question for clinical chemists using an AI program: "Should labs eliminate CK-MB testing?" The results of this inquiry were critically reviewed by a cardiologist, emergency department physician, and clinical laboratorians for accuracy and appropriateness.
Open shell versus closed shell bonding interaction in cyclopropane derivatives: EDA-NOCV analyses.
J Comput Chem
October 2023
Department of Chemistry, Indian Institute of Technology Madras, Chennai, India.
Cyclopropane ring is a very common motif in organic/bio-organic compounds. The chemical bonding of this strained ring is taught to all chemistry students. This three-membered cyclic, C ring is quite reactive which has attracted both, synthetic and theoretical chemists to rationalize/correlate its stability and bonding with its reactivity and physical properties over a century.
View Article and Find Full Text PDFPharmacological strategies to manage hyperkalaemia: out with the old, in with the new? Not so fast….
Clin Kidney J
August 2023
Department of Medicine, McMaster University, Hamilton, Ontario, Canada.
Since the 1950s, sodium polystyrene sulphonate (SPS) has been the dominant cation exchange agent prescribed for hyperkalaemia. Clinicians have had plenty of time to learn of SPS's advantages and limitations. The demands of drug regulatory agencies regarding the incorporation of medications into the market were not so stringent then as they are today, and the efficacy and safety of SPS have been questioned.
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