Spatial and temporal variation of methane emissions in the coastal Balearic Sea, Western Mediterranean.

Methane (CH) gas is the most important GHG after carbon dioxide, with open ocean areas acting as discreet CH sources and coastal regions as intense but variable CH sources to the atmosphere. Here, we report CH concentrations and air-sea fluxes in the coastal area of the Balearic Islands Archipelago (Western Mediterranean Basin). CH levels and related biogeochemical variables were measured in three coastal sampling sites between 2018 and 2021, with two located close to the densely populated island of Mallorca and one in a pristine area in the Cabrera Archipelago National Park. CH concentrations in seawater during the study period ranged from 2.7 to 10.9 nM, without significant differences between the sampling sites. Averaged estimated CH fluxes during the sampling period for the three stations oscillated between 0.2 and 9.7 μmol m d according to a seasonal pattern and in general all sites behaved as weak CH sources throughout the sampling period.