Fine-Tuned Ultra-Microporous Metal-Organic Framework in Mixed-Matrix Membrane: Pore-Tailoring Optimization for C H /C H Separation.

Effective separation of ethyne from ethyne/ethylene (C H /C H ) mixtures is a challenging and crucial industrial process. Herein, an ultra-microporous metal-organic framework (MOF) platform, Cd(dicarboxylate) (ditriazole), with triangular channels is proposed for high-efficiency separation of C H from C H . The targeted structures are constructed via a mixed-ligand strategy by selecting different-sized ligands, allowing for tunable pore sizes and volumes. The pore properties can be further optimized by additional modification via pore environment tailoring. This concept leads to the successful synthesis of three ultra-microporous Cd-MOFs (JLU-MOF87-89). As intended, C H uptake and C H /C H selectivity gradually increase with progressively optimizing the pore structure by adjusting ligand length and substituents. JLU-MOF89, functionalized with methyl groups, features the most optimal pore chemistry and shows selective recognition of C H over C H , owing to the framework-C H host-guest interactions. Furthermore, JLU-MOFs are fabricated into mixed-matrix membranes for C H /C H separation. C H permeability and C H /C H permselectivity are substantially enhanced by ≥400% and ≥200%, respectively, after hybridization of JLU-MOF88 and JLU-MOF89 with a polyimide polymer (6FDA-ODA). These membranes can work efficiently and are stable under different conditions, demonstrating their potential in actual ethyne separation.