Zinc ions (Zn) and cadmium ions (Cd) are widely present in our production and life, which are closely related to human health and environmental protection. Hence, it is essential to detect their concentrations. Herein, we developed a convenient and reliable small-molecule fluorescent probe based on Schiff base of dicyanisophorone and 2-hydrazinopyridine. This probe can be able to selectively detect Zn and Cd, showing the advantages of near-infrared emission (the maximum emission wavelength: 668 nm), good selectivity, high sensitivity (the detection limits: 0.21 µM and 0.31 µM, respectively) and rapid response (15 s). It has excellent potential for rapid testing and visual tracking of Zn and Cd in aqueous solution and living cells.
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http://dx.doi.org/10.1016/j.saa.2022.122243 | DOI Listing |
Spectrochim Acta A Mol Biomol Spectrosc
April 2023
College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, Guangxi 541006, PR China. Electronic address:
Zinc ions (Zn) and cadmium ions (Cd) are widely present in our production and life, which are closely related to human health and environmental protection. Hence, it is essential to detect their concentrations. Herein, we developed a convenient and reliable small-molecule fluorescent probe based on Schiff base of dicyanisophorone and 2-hydrazinopyridine.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
May 2022
Nanjing Tech University, No. 30, South Puzhu Road, Nanjing 211816, China. Electronic address:
This article reports a new type of dicyanisophorone-based near-infrared fluorescent probe for the rapid detection of mercaptophenol by introducing 2,4-dinitrobenzene sulfonate group as a specific recognition group for thiophenol. The probe has a significant large Stokes shift (185 nm). At the same time, it exhibits rapid response, high selectivity and high sensitivity to thiophene.
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