Detailed information on the variation of soil clay content at different soil depths are important for water repellency, management of soil fertility, and crop growth. However, studies on the variation of soil clay content at different depths at large scales are limited. In this study, 1446 soil profiles covering most areas of China were extracted from the World Soil Information Service (WoSIS) database and classified into 0-20, 20-60, and 60-100 cm depths using the equal-area quadratic splines. Random forest (RF) and Shapley additive explanations (SHAP) were used to investigate the relationship between soil clay content and environmental factors (climate, topography, land use, and soil types). The results showed that soil clay content and its variability increased with soil depth. The RF model predicted soil clay content at the three soil depths. The mean absolute error (MAE), root mean square error (RMSE), coefficient of determination (R), and Lin's concordance correlation coefficient (CCC) ranged from 6.95 % to 8.74 %, 8.90 % to 11.30 %, 42 % to 46 %, and 56 % to 59 %, respectively. Mean annual temperature (MAT), mean annual precipitation (MAP), solar radiation (solarR), and elevation were the key factors that controlled the variation of soil clay content at depths of 0-20, 20-60, and 60-100 cm. In addition, the main effect values of SHAP can identify environmental thresholds consistent with significant areas by capturing the relationship between soil clay content and MAT, MAP, solarR, and elevation. Significant differences were found in soil clay content on both sides of the threshold at MAT of 15 °C, MAP of 800 mm, solarR of 15,000 Jm yr, and elevation of 1200 m. The results provide clues to the management of national soil security under global and regional climate change.
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http://dx.doi.org/10.1016/j.scitotenv.2022.161141 | DOI Listing |
Heliyon
January 2025
ICAR-IIRR, Indian Institute of Rice Research, Hyderabad, 500 030, India.
Arbuscular mycorrhizal Fungi (AMF) are essential in agriculture and are often inter-linked with glomalin-related soil protein (GRSP) production which supports binding of aggregates, enhanced SOC and biological attributes. However, conservation agricultural practices in agroecosystem may have significant impact on AMF diversity, GRSP and soil quality-related parameters (SQRPs). This current experiment was implemented to gauge AMF conization percentage (AMF-CP), GSRP and significant changes on critical SQRPs, and to investigate the linkages between AMF-CP, GRSP and SQRPs as influenced by synergistic tillage and weed management in CA.
View Article and Find Full Text PDFEnviron Sci Technol
January 2025
State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, PR China.
Cadmium (Cd) isotopes have recently emerged as novel tracers of Cd sources and geochemical processes. Widespread clay minerals play a key role in Cd migration due to their strong adsorption capacity, but the mechanism of Cd isotope fractionation during adsorption onto clay minerals is poorly understood. Here, we experimentally investigated the adsorption mechanisms of Cd on montmorillonite (2:1) and kaolinite (1:1) by using extended X-ray absorption fine structure (EXAFS) spectroscopy.
View Article and Find Full Text PDFEnviron Geochem Health
January 2025
Department of Agricultural Chemistry, National Taiwan University, Taipei, 10617, Taiwan.
Rare earth elements (REEs) are a critical global focus due to their increasing use, raising concerns about their environmental distribution and human exposure, both vital to food safety and human health. Surface soil (0-30 cm) and corresponding rice grain samples (n = 85) were collected from paddy fields in Taiwan. This study investigated the total REE contents in soil through aqua regia digestion, as well as their labile forms extracted using 0.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
PG & Research Department of Physics, AVVM Sri Pushpam College (Autonomous), [Affiliated to Bharathidasan University, Tiruchirappalli], Poondi, Thanjavur 613503, Tamil Nadu, India. Electronic address:
Development of bio-supported photocatalysts has become a pressing need in the field of environmental remediation. This work reports the synthesis of bio-enzyme (from banana peels) inherited (ZnO/g-CN) nanocomposite by simple soft chemical method and its photocatalytic degradation ability against the mixed dye (Methylene blue (MB) + Rhodamine-B (RhB)) under UV irradiation. Synthesized nanoparticles were characterized using experimental techniques XRD, FESEM, TEM, EDAX, XPS, UV-vis-NIR spectroscopy and FTIR.
View Article and Find Full Text PDFEnviron Res
January 2025
Departamento de Bioloxía Vexetal e Ciencias do Solo, Área de Edafoloxía e Química Agrícola, Facultade de Ciencias, Universidade de Vigo, As Lagoas s/n, Ourense, 32004, Spain; Instituto de Agroecoloxía e Alimentación (IAA), Campus Auga, Universidade de Vigo, Ourense, 32004, Spain; Comunidades Microbianas de suelos (id. UA 1678), MBG-CSIC/ Universidad de Vigo, Unidad asociada al CSIC, Spain.
The overuse of pesticides in agriculture has led to widespread pollution of soils and water resources, becoming a problem of great concern. Nowadays, special attention is given to neonicotinoids, particularly acetamiprid, the only neonicotinoid insecticide allowed for outdoor use in the European Union. Once acetamiprid reaches the soil, adsorption/desorption is the main process determining its bioavailability and environmental fate.
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