Symmetry Breaking in Sticky Collisions between Ultracold Molecules.

Phys Rev Lett

Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, Netherlands.

Published: December 2022

AI Article Synopsis

  • Ultracold molecules can experience "sticky collisions" that cause loss even without chemical reactions.
  • These collisions can have greatly increased sticking times through interactions that disrupt nuclear spin or total angular momentum.
  • Our study shows that weak electric fields can disrupt angular momentum conservation, while nuclear spin remains conserved, and we analyze the slow loss rates from spontaneous emission and black-body radiation.

Article Abstract

Ultracold molecules undergo "sticky collisions" that result in loss even for chemically nonreactive molecules. Sticking times can be enhanced by orders of magnitude by interactions that lead to nonconservation of nuclear spin or total angular momentum. We present a quantitative theory of the required strength of such symmetry-breaking interactions based on classical simulation of collision complexes. We find static electric fields as small as 10  V/cm can lead to nonconservation of angular momentum, while we find nuclear spin is conserved during collisions. We also compute loss of collision complexes due to spontaneous emission and absorption of black-body radiation, which are found to be slow.

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Source
http://dx.doi.org/10.1103/PhysRevLett.129.243401DOI Listing

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