Solid-State Synthesis of Cobalt/NCS Electrocatalyst for Oxygen Reduction Reaction in Dual Chamber Microbial Fuel Cells.

Due to the high cost of presently utilized Pt/C catalysts, a quick and sustainable synthesis of electrocatalysts made of cost-effective and earth-abundant metals is urgently needed. In this work, we demonstrated a mechanochemically synthesized cobalt nanoparticles supported on N and S doped carbons derived from a solid-state-reaction between zinc acetate and 2-amino thiazole as metal, organic ligand in presence of cobalt (Co) metal ions ZnCo(CHNS). Pyrolysis of the ZnCo(CHNS) produced, Co/NSC catalyst in which Co nanoparticles are evenly distributed on the nitrogen and sulfur doped carbon support. The Co/NSC catalyst have been characterized with various physical and electrochemical characterization techniques. The Co content in the ZnCo(CHNS) is carefully adjusted by varying the Co content and the optimized Co/NSC-3 catalyst is subjected to the oxygen reduction reaction in 0.1 M HClO electrolyte. The optimized Co/NSC-3 catalyst reveals acceptable ORR activity with the half-wave potential of ~0.63 V vs. RHE in acidic electrolytes. In addition, the Co/NSC-3 catalyst showed excellent stability with no loss in the ORR activity after 10,000 potential cycles. When applied as cathode catalysts in dual chamber microbial fuel cells, the Co/NCS catalyst delivered satisfactory volumetric power density in comparison with Pt/C.