With the rapid development of modern industries, water pollution has become an urgent problem that endangers the health of human and wild animals. The photocatalysis technique is considered an environmentally friendly strategy for removing organic pollutants in wastewater. As an important member of Bi-series semiconductors, BiWO is widely used for fabricating high-performance photocatalysts. In this review, the recent advances of BiWO-based photocatalysts are summarized. First, the controllable synthesis, surface modification and heteroatom doping of BiWO are introduced. In the respect of BiWO-based composites, existing BiWO-containing binary composites are classified into six types, including BiWO/carbon or MOF composite, BiWO/g-CN composite, BiWO/metal oxides composite, BiWO/metal sulfides composite, BiWO/Bi-series composite, and BiWO/metal tungstates composite. BiWO-based ternary composites are classified into four types, including BiWO/g-CN/X, BiWO/carbon/X, BiWO/Au or Ag-based materials/X, and BiWO/Bi-series semiconductors/X. The design, microstructure, and photocatalytic performance of BiWO-based binary and ternary composites are highlighted. Finally, aimed at the existing problems in BiWO-based photocatalysts, some solutions and promising research trends are proposed that would provide theoretical and practical guidelines for developing high-performance BiWO-based photocatalysts.
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http://dx.doi.org/10.3390/molecules27248698 | DOI Listing |
Org Lett
January 2025
Key Laboratory for Green Pharmaceutical Technologies and Related Equipment of Ministry of Education, College of Pharmaceutical Sciences, Zhejiang University of Technology, Hangzhou 310014, P. R. China.
Herein, a -phenylphenothiazine-based hyper-cross-linked polymer (PTH-HCP) was finely designed and constructed, which serves as a metal-free heterogeneous photocatalyst for organic transformations. Characterization experiments have shown that this polymer demonstrates outstanding stability, extensive surface area, and exceptional photoelectric response properties. Moreover, PTH-HCP showed good catalytic efficiency and recyclability in the photochemically driven difluoromethylation/cyclization reactions.
View Article and Find Full Text PDFEnviron Res
January 2025
Faculty for Chemistry, Department of Physical Chemistry, University of Vienna, Vienna, Austria.
Composite photocatalysts based on metal nanoparticles and functional polymers attract much attention compared to inorganic photocatalysts. In this study, a reusable magnetite/anion exchanger (FeO/PPE-2) functional material is synthesized by a hydrothermal method, and its photocatalytic activity is evaluated for the photocatalytic degradation of Rhodamine B (RhB). The results from materials characterization confirm a well-defined morphology of magnetic FeO/PPE-2 functional material and the formation of FeO nanocrystals with different shapes and sizes on the surface of anion exchange material (PPE-2).
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164 PR China.
The development of heterojunctions is a proven strategy to augment the photocatalytic efficiency of materials. However, the enhancement in charge transfer facilitated by a single heterojunction is inherently constrained. To overcome these limitations, we synthesized a dual S-scheme heterojunction ternary composite photocatalyst, CuO/NiAl-LDH@MIL-53(Fe), designed for efficient visible-light-driven hydrogen (H) production.
View Article and Find Full Text PDFNanotechnology
January 2025
Qingdao University, Ningxia Road 308, Qingdao, Shandong, 266071, CHINA.
Graphitic carbon nitride (g-C3N4) has gained significant attention as a promising nonmetallic semiconductor photocatalyst due to its photochemical stability, favorable electronic properties, and efficient light absorption. Nevertheless, its practical applications are hindered by limitations such as low specific surface area, rapid recombination of photogenerated charge carriers, poor electrical conductivity, and restricted photo-response ranges. This review explores recent advancements in the synthesis, modification and application of g-C3N4 and its nanocomposites with a focus on addressing these challenges.
View Article and Find Full Text PDFOrg Lett
January 2025
Department of Chemistry and Materials Science, College of Science, Nanjing Forestry University, Nanjing 210037, China.
The Nozaki-Hiyama-Kishi reaction offers effective and reliable strategies for the preparation of alcohols via carbon-carbon bond formation. Typical methods usually require stoichiometric amounts of chromium salts, co-transition metals, and auxiliary reagents, which limits their practical application in industrial chemistry. To mitigate these limitations, substantial efforts have been made to develop chromium-catalytic approaches.
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