The thermoelectric power-factor of two types of rutile-phased nanostructured-TiO thin films doped with Ag was investigated at room temperature, by measuring their Seebeck coefficient and electrical conductivity. The thin films, consisting of a nanorod structure (single layer) and nanorod and nanoflower structure (bilayer) of TiO with the addition of different wt.% of AgNO were synthesized on an F:SnO-coated glass substrate. The evaluated thermoelectric power-factor was observed to increase with an increasing wt.% of AgNO for both structures, with the bilayer structure increasing three times more than the undoped bilayer-structure, with a value of 148 μWm-K at 0.15 wt.%. This enhancement was due to the increase in electrical conductivity, which compensated for the small changes in the Seebeck coefficient, which were likely due to the increase in carrier concentration. Consequently, an enhancement in the thermoelectric conversion-efficiency of TiO thin film may be observed by Ag doping, without influencing the layer structure and material phase.
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http://dx.doi.org/10.3390/mi13122169 | DOI Listing |
Materials (Basel)
January 2025
Department of Polymer Engineering, Pukyong National University, Busan 48513, Republic of Korea.
Carbon nanotubes (CNTs) have drawn great attention as promising candidates for realizing next-generation printed thermoelectrics (TEs). However, the dispersion instability and resulting poor printability of CNTs have been major issues for their practical processing and device applications. In this work, we investigated the TE characteristics of water-processable carboxymethyl cellulose (CMC) and single-walled CNT (SWCNT) composite.
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January 2025
Department of Physics, Michigan Technological University, Houghton, MI 49931, USA.
ZnSb is widely recognized as a promising thermoelectric material in its bulk form, and a ZnSb bilayer was recently synthesized from the bulk. In this study, we designed a vertical van der Waals heterostructure consisting of a ZnSb bilayer and an h-BN monolayer to investigate its electronic, elastic, transport, and thermoelectric properties. Based on density functional theory, the results show that the formation of this heterostructure significantly enhances electron mobility and reduces the bandgap compared to the ZnSb bilayer, thereby increasing its power factor.
View Article and Find Full Text PDFSmall
January 2025
Key Lab of Photovoltaic and Energy Conservation Materials, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei, 230031, P. R. China.
N-type BiTeSe(BTS) is a state-of-the-art thermoelectric material owing to its excellent thermoelectric properties near room temperatures for commercial applications. However, its performance is restricted by its comparatively low figure of merit ZT. Here, it is shown that a 14% increase in power factor (PF) (at 300 K) can be reached through incorporation of inorganic GaAs nanoparticles due to enhanced thermopower originating from the energy-dependent carrier scattering.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
SKKU Advanced Institute of Nanotechnology (SAINT) and Department of Nano Science and Technology, Sungkyunkwan University, Suwon, 16419, Republic of Korea.
A novel additive method to boost the Seebeck coefficient of doped conjugated polymers without a significant loss in electrical conductivity is demonstrated. Perovskite (CsPbBr) quantum dots (QDs) passivated by ligands with long alkyl chains are mixed with a conjugated polymer in a solution phase to form polymer-QD blend films. Solution sequential doping of the blend film with AuCl solution not only doped the conjugated polymer but also decomposed the QDs, resulting in a doped conjugated polymer film embedded with separated ions dissociated from the QDs.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Physics, Riphah International University, Islamabad 44000, Pakistan.
Halide perovskites are a class of materials with excellent potential for solar cell applications due to their excellent optical and electronic properties. In this study, strain-dependent physical properties of SrNBr perovskites are investigated and theoretical results are reported here. The structural properties indicate that SrNBr has a cubic structure.
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