We define common thermodynamic concepts purely within the framework of general Markov chains and derive Jarzynski's equality and Crooks' fluctuation theorem in this setup. In particular, we regard the discrete-time case, which leads to an asymmetry in the definition of work that appears in the usual formulation of Crooks' fluctuation theorem. We show how this asymmetry can be avoided with an additional condition regarding the energy protocol. The general formulation in terms of Markov chains allows transferring the results to other application areas outside of physics. Here, we discuss how this framework can be applied in the context of decision-making. This involves the definition of the relevant quantities, the assumptions that need to be made for the different fluctuation theorems to hold, as well as the consideration of discrete trajectories instead of the continuous trajectories, which are relevant in physics.
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http://dx.doi.org/10.3390/e24121731 | DOI Listing |
Sensors (Basel)
January 2025
Department of Academic Respiratory Medicine, Centre for Cardiovascular and Metabolic Research, Hull York Medical School, Cottingham HU16 5JQ, UK.
Coughing is a symptom of many respiratory diseases. An increased amount of coughs may signal an (upcoming) health issue, while a decreasing amount of coughs may indicate an improved health status. The presence of a cough can be identified by a cough classifier.
View Article and Find Full Text PDFACS Photonics
January 2025
Center for Nanophotonics, AMOLF, Science Park 104, XG Amsterdam 1098, the Netherlands.
We present a complete framework of stochastic thermodynamics for a single-mode linear optical cavity driven on resonance. We first show that the steady-state intracavity field follows the equilibrium Boltzmann distribution. The effective temperature is given by the noise variance, and the equilibration rate is the dissipation rate.
View Article and Find Full Text PDFPhys Rev E
June 2024
Dipartimento di Fisica e Astronomia and Sezione INFN, Università di Padova, Via Marzolo 8, 35131 Padova, Italy.
Fluctuation theorems are fundamental results in nonequilibrium thermodynamics beyond the linear response regime. Among these, the paradigmatic Tasaki-Crooks fluctuation theorem relates the statistics of the works done in a forward out-of-equilibrium quantum process and in a corresponding backward one. In particular, the initial states of the two processes are thermal states and thus incoherent in the energy basis.
View Article and Find Full Text PDFPhys Rev Lett
November 2023
Centre for Quantum Technologies, National University of Singapore, 3 Science Drive 2, Singapore 117543, Singapore.
The interplay between thermodynamics and information theory has a long history, but its quantitative manifestations are still being explored. We import tools from expected utility theory from economics into stochastic thermodynamics. We prove that, in a process obeying Crooks's fluctuation relations, every α Rényi divergence between the forward process and its reverse has the operational meaning of the "certainty equivalent" of dissipated work (or, more generally, of entropy production) for a player with risk aversion r=α-1.
View Article and Find Full Text PDFBiophys Rev
December 2022
Artificial Intelligence Research Center, National Institute of Advanced Industrial Science and Technology (AIST), 2-4-7 Aomi, Koto-Ku, Tokyo, 135-0064 Japan.
Non-equilibrium molecular dynamics (NEMD) simulation has been recognized as a powerful tool for examining biomolecules and provides fruitful insights into not only non-equilibrium but also equilibrium processes. We review recent advances in NEMD simulation and relevant, fundamental results of non-equilibrium statistical mechanics. We first introduce Crooks fluctuation theorem and Jarzynski equality that relate free energy difference to work done on a physical system during a non-equilibrium process.
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