Described here is a unprecedented organophotoredox/manganese dual catalyzed proton reduction and its application for semi-reduction of alkynes. The catalytic active pre-catalyst [Mn-1] can be feasibly be prepared on gram-scale from Mn(acac)·2HO in air. This dual catalytic protocol features noble-metal-free catalysts, simple ligand, and mild conditions. Besides, a unique -halogen and -hydroxyl effect was observed to achieve high -stereoselectivity.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9761695 | PMC |
| http://dx.doi.org/10.1039/d2ra07920h | DOI Listing |
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