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Currently, replacing expensive and short-lived materials for supercapacitors based on RuO with more cost-effective and high-performance materials that remain operational after a large number of cycles is a challenge. Cerium-based materials are the most attractive alternative because of cerium's ability to quickly change oxidation state. This work proposes the synthesis of nanostructured graphene-ceria composite and studies its morphological features arising under the impact of oxygen-free graphene.

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Facile Synthesis of Sandwich-Type Porous Structured Ni(OH)/NCNWs/rGO Composite for High Performance Supercapacitor.

Molecules

February 2025

Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252059, China.

Nickel hydroxide has ultra-high energy storage capacity in supercapacitors, but poor electrical conductivity limits their further application. The use of graphene to improve its conductivity is an effective measure, but how to suppress the stacking of graphene and improve the overall performance of composite materials has become a new challenge. In this work, a well-designed substrate of N-doped carbon nanowires with reduced graphene oxide (NCNWs/rGO) was fabricated by growing polypyrrole (PPy) nanowires between GO nanosheets layers and then calcining them at high temperatures.

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Facile Electret Fabrication for Energy Harvesting from Human Gait.

Polymers (Basel)

February 2025

Dipartimento di Fisica and Centro di Ricerca Interdipartimentale in Materiali Avanzati e Dispositivi (MADE), Università degli Studi di Pavia, Via A. Bassi 6, 27100 Pavia, Italy.

Dielectric elastomer generators (DEGs) are electrostatic transducers capable of harvesting electrical energy from oscillating mechanical parts and storing it in a battery or supercapacitor. The energy conversion element typically consists of a flexible capacitor with a variable capacitance that depends on the applied stress cycle and requires an external voltage source (bias voltage). In designing an energy harvesting device from human gait, we propose integrating two components: a dielectric elastomer fabricated using a nanocomposite polyurethane (TPU-CaCuTiO) and an electret serving as a bias voltage source.

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Synthesis of hollow hierarchical porous carbon spheres from lignin by soft template and hydrothermal method for supercapacitors.

Int J Biol Macromol

March 2025

College of Environmental Science and Engineering, Nankai University, No. 38, Tongyan Road, Jinnan District, Tianjin 300350, China. Electronic address:

Among the various carbon-based electrode materials, porous carbon spheres stand out for their exceptional properties, such as high specific surface area (SSA), high percussion density, and distinctive surface chemistry, which are conducive to uniform surface modification and acceleration of electrolyte diffusion, thereby enhancing the energy density of battery. Hollow carbon spheres, with their unique structure, are drawing increasing attention for their potential applications in energy storage devices. In this work, hollow hierarchical porous carbon spheres (HPCS) were synthesized by one-pot method using alkali lignin extracted from corn straw as carbon precursor, CTAB as template agent, Zn as crosslinking agent and KHCO as activator.

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A Novel Coating-Extrusion Method Enabled, High Energy, Power Density, and Scalable Production in Monolithically Integrated Energy Storage Fibers.

Adv Mater

March 2025

State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Institute of Fiber Materials and Devices, Department of Chemistry and Laboratory of Advanced Materials, Fudan University, Shanghai, 200438, China.

The rise of wearable electronics demands flexible energy storage solutions like flexible fiber energy storage devices (FESDs), known for their flexibility and portability. However, it remains difficult for existing fabrication methods (typically, finite-coating, thermal-drawing, and solution-extrusion) to simultaneously achieve desirable electrochemical performances and fast production of FESDs. Here, a new scalable coating-extrusion method is developed, utilizing a novel extruded spinneret with tapered apertures to create dual pressure zones.

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