The development of new photocatalysts with high photocatalytic efficiency and catalytic stability, and long persisting luminescence is critical for ensuring environmental protection and clean energy production. In this study, we develop a flower-like InO/ZnGaO:Cr heterojunction composite with enhanced ultraviolet (UV) photocatalytic activity using a facile two-step hydrothermal method. The spectral response range of the heterojunction composite is widened to the visible-light range owing to the presence of the ZnGaO:Cr persistent luminescence nanoparticles with sizes of less than 10 nm. The heterojunction composite is dispersed on the flower petals of InO. The InO/ZnGaO:Cr/1:1 composite exhibits photo-degradation performance for rhodamine B degradation that is superior to those of pure InO, ZnGaO:Cr, InO/ZnGaO:Cr/1:0.5 and InO/ZnGaO:Cr/1:2, achieving complete degradation after 80 min under UV light irradiation. Moreover, it exhibits long afterglow luminescence that lasts for more than 72 h. Thus, the InO/ZnGaO:Cr/1:1 composite shows great potential for use in round-the-clock photocatalytic applications.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9727685PMC
http://dx.doi.org/10.1039/d2ra05646aDOI Listing

Publication Analysis

Top Keywords

heterojunction composite
16
photocatalytic activity
8
flower-like ino/zngaocr
8
ino/zngaocr heterojunction
8
long persisting
8
persisting luminescence
8
ino/zngaocr/11 composite
8
composite
6
enhanced photocatalytic
4
activity flower-like
4

Similar Publications

Hydrogen evolution from water, catalyzed by solar energy, is a promising yet challenging endeavor. Small-sized catalysts usually exhibit high utilization and high performance in the hydrogen evolution field. However, the high surface energy tends to make them aggregate.

View Article and Find Full Text PDF

Piezoelectric catalysis possesses the potential to convert ocean wave energy into and holds broad prospects for extracting uranium from seawater. Herein, the Z-type ZnO@COF heterostructure composite with excellent piezoelectric properties was synthesized through in situ growth of covalent organic frameworks (COFs) on the surface of ZnO and used for efficient uranium extraction. The designed COFs shell enables ZnO with stability, abundant active sites and high-speed electron transport channels.

View Article and Find Full Text PDF

This work aimed at addressing the problem of hexavalent chromium pollution in the water environment, designing and preparing the Cu/CuO/NH-MIL-88B (Fe) heterojunction material with NH-MIL-88B (Fe) as the carrier, Cu/CuO was loaded on NH-MIL-88B (Fe) by light-assisted reduction. The loading of CuO effectively improves the visible light absorption capacity of the composite material. The SPR effect of Cu improves the separation and transfer of photogenerated carriers in the composite material.

View Article and Find Full Text PDF

Metal-free photocatalysts derived from earth-abundant elements have drawn significant attention owing to their ample supply for potential large-scale applications. However, it is still challenging to achieve highly efficient photocatalytic performance owing to their sluggish charge separation and lack of active catalytic sites. Herein, we designed and constructed a series of covalently bonded organic semiconductors to enhance water splitting and phenol degradation.

View Article and Find Full Text PDF

Hollow TiO@TpPa S-Scheme Photocatalyst for Efficient HO Production Through O in Deionized Water Using Phototautomerization.

Small

January 2025

Laboratory of Solar Fuel, Faculty of Materials Science and Chemistry, China University of Geosciences, 68 Jincheng Street, Wuhan, Hubei, 430078, P. R. China.

Hydrogen peroxide (HO) production through photocatalytic O reduction reaction (ORR) is a mild and cost-efficient alternative to the anthraquinone oxidation strategy. Of note, singlet state oxygen (O) plays a crucial role in ORR. Herein, a hollow TiO@TpPa (TOTP) S-scheme heterojunction by the Schiff base reactions involving 1,3,5-triformylphloroglucinol (Tp) and paraphenylenediamine (Pa) for efficient photocatalytic HO production in deionized water has been developed.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!