Probing borafluorene B-C bond insertion with gold acetylide and azide.

Dalton Trans

Baylor University, Department of Chemistry and Biochemistry, One Bear Place #97348, Waco, TX 76798, USA.

Published: January 2023

The reaction of PhPAuN with 9-Ph-9-borafluorene resulted in complexation of the azide to boron while a gold acetylide reacted with 9-Ph-9-borafluorene to insert the acetylide carbon to access a six-membered boracycle with an exocyclic double bond.

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http://dx.doi.org/10.1039/d2dt03672jDOI Listing

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