B(CF)-catalyzed metal-free hydrogenation of 2-oxazolones.

Org Biomol Chem

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Published: January 2023

A metal-free hydrogenation of 2-oxazolones was successfully realized by using 10 mol% of B(CF) as the catalyst, giving a variety of 2-oxazolidinones in 70-98% yields. An enamine to imine process was believed to be involved in this reaction.

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Source
http://dx.doi.org/10.1039/d2ob01950gDOI Listing

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