Dioxin-like POPs emission trends as a decision support tool for developing sustainable MSW management scheme -an exploratory study.

The paper reports on an innovative application of dioxin-like persistent organic pollutants (dl-POPs) emission trends as a measure of environmental performance for designing feasible municipal solid waste management (MSWM) schemes. MSWM systems are highly dependent on the income status and the population density and it is quintessential for developing countries to devise strategies suiting to its characteristics rather than simply adapting successful processes/technologies in developed nations. Hence a lower-middle-income, high-density populated state of India - Kerala, which represents the typical scenario of majority of towns in developing countries was selected as the verification study site. Annual inventorisation of dl-POPs for the current scenario of the state was developed as a spatial model at the lowest administrative block level using geographical information system for the easy and effective comparative assessment. Further, a dl-POPs emission based MSWM scheme which could reduce up to 65% of emissions from current scenario has been developed and compared it with contemporary life cycle assessment (LCA) and life cycle cost analysis (LCCA) schemes in terms of green-house gas emissions (GHG) and landfill area requirements as environmental performance validation. Daily exposure dose of dl-POPs were predicted from the per-capita annual emission associated with different MSWM schemes and hazard quotients were also calculated to provide an overview of the health risk posed by the emissions. The predicted health risk factors were observed to be 5 times higher than the threshold level in current scenario whereas 10 times reduction in dose levels could be achieved through the proposed scheme of MSWM.