Herein, we disclose a new photoredox-catalysed strategy to access -difluoroallylarenes from α-trifluoromethylalkenes with sterically hindered primary amines C-N and C-F bond activation. This deaminative and defluorinative allylation is generally compatible with diverse functional groups and sterically hindered α-3° and 2° primary amines.
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| http://dx.doi.org/10.1039/d2ob02114e | DOI Listing |
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