AI Article Synopsis

Article Abstract

In this work, we report the first selective, photocatalyzed [2+2]-cycloaddition of dehydroamino acids with styrene-type olefins. This simple, mild, and scalable approach relies on the use of the triplet energy transfer catalyst [Ir(dFCFppy)dtbpy]PF under visible light irradiation and provides fast access to value-added substituted strained cyclobutane α-amino acid derivatives.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9732878PMC
http://dx.doi.org/10.1021/acsorginorgau.2c00026DOI Listing

Publication Analysis

Top Keywords

cyclobutane α-amino
8
visible light
8
direct access
4
access unnatural
4
unnatural cyclobutane
4
α-amino acids
4
acids visible
4
light catalyzed
4
catalyzed [2+2]-cycloaddition
4
[2+2]-cycloaddition work
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!