A metal-free catalytic oxidation of α-diazoesters a green environmental-friendly route was developed. The α-diazoesters were converted to α-ketoesters using DMF and molecular oxygen as oxygen sources and B(CF) as the catalyst, without any additives. This protocol has a broad adaptability of substrates and good compatibility with a range of functional groups, and it offers new insight into reactions catalyzed by B(CF).
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9682326 | PMC |
| http://dx.doi.org/10.1039/d2ra05739e | DOI Listing |
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