The COVID-19 pandemic has increased the need for developing disinfectant surfaces as well as reducing the spread of infections on contaminated surfaces and the contamination risk from the fomite route. The present work reports on the antiviral activity of coatings containing ZnO particles obtained by two simple synthesis routes using Aloe vera (ZnO-aloe) or cassava starch (ZnO-starch) as reaction fuel. After detailed characterization using XRD and NEXAFS, the obtained ZnO particles were dispersed in a proportion of 10% with two different waterborne acrylic coatings (binder and commercial white paint) and brushed on the surface of polycarbonates (PC). The cured ZnO/coatings were characterized by scanning electron microscopes (SEM) and energy-dispersive X-ray spectroscopy (EDS). Wettability tests were performed. The virucidal activity of the ZnO particles dispersed in the waterborne acrylic coating was compared to a reference control sample (PC plates). According to RT-PCR results, the ZnO-aloe/coating displays the highest outcome for antiviral activity against SARS-CoV-2 using the acrylic binder, inactivating >99% of the virus after 24 h of contact relative to reference control.
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http://dx.doi.org/10.3390/nano12234345 | DOI Listing |
Int J Mol Sci
December 2024
Department of Wood Science and Thermal Techniques, Faculty of Forestry and Wood Technology, Poznan University of Life Sciences, ul. Wojska Polskiego 38/42, 60-637 Poznan, Poland.
This research investigated the selected properties of nanocellulose films intended to serve as protective patches on fissured surfaces of wooden artefacts. The effects of their plasticisation with glycerol and functionalisation with selected silanes ((3-Glycidyloxypropyl)trimethoxysilane, and Methyltrimethoxysilane) were also determined. The obtained pure cellulose nanopapers (CNPs) had a homogeneous and compact structure but were very brittle, stiff, and wavy.
View Article and Find Full Text PDFRSC Adv
December 2024
School of Materials Science and Technology, Beijing Key Laboratory of Wooden Material Science and Application, Beijing Forestry University Haidian Beijing 100083 China
A root-like waterborne hyperbranched polymer, synthesized from diethylenetriamine (DETA) and methyl acrylate (MA) monomers, was inspired by the effect of solidifying soil with tree roots. This polymer was then blended with aqueous isocyanate SK615, known as MD-HBP-NH, to serve as a surface modifier for blockboards. The blockboards were treated with a modifier to enhance the interfacial adhesion with melamine-formaldehyde (MF) resin-impregnated decorative paper, thereby preventing surface cracks.
View Article and Find Full Text PDFSci Rep
December 2024
POLYMAT and Departamento de Química Aplicada, Facultad de Ciencias Químicas, University of the Basque Country UPV/EHU, Joxe Mari Korta Zentroa, Tolosa hiribidea, 72, 20018, Donostia, Spain.
The anti-polyelectrolyte effect, a characteristic unique to polymer chains containing zwitterions, was investigated for its impact on colloidal stabilization during emulsion polymerization and on the resulting polymer characteristics. The zwitterionic monomer (ZM) 3-[(3-Acrylamidopropyl)dimethylammonio]propane-1-sulfonate (A3361) was selected for the synthesis of 30 wt% emulsifier-free methyl methacrylate/n-butyl acrylate (MMA/n-BA) polymer latex. Three pH conditions were examined: neutral, where the zwitterionic chains are in a collapsed state, and acidic and basic, where these chains adopt an extended conformation, leading to the anti-polyelectrolyte effect.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601, Japan.
Efforts to improve the energy density and cycling stability of lithium-ion batteries have focused on replacing LiCoO in cathodes with LiNiMnCoO. However, reliance on polyvinylidene fluoride (PVdF) as the binder limits the application of the LiNiMnCoO composite electrode for lithium-ion batteries. Here, we evaluate the electrochemical properties of a LiNiMnCoO (NMC111) powder electrode formed using a waterborne-styrene-acrylic-rubber (SAR) latex binder combined with sodium carboxymethylcellulose.
View Article and Find Full Text PDFMaterials (Basel)
October 2024
Department of Chemistry and NIS Centre, University of Turin, Via Pietro Giuria 7, 10125 Torino, Italy.
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