AI Article Synopsis
- A new Rh-catalyzed method for propenylating C(sp)-H bonds using -allyl benzimidazole has been successfully developed.
- This is the first report of this transformation, showcasing a tandem process that involves C-H allylation followed by alkene isomerization for a highly selective -propenylated product.
- Comprehensive mechanistic studies were carried out, characterizing intermediate rhodacycles to gain insights into the reaction mechanism.
Article Abstract
A Rh-catalyzed C(sp)-H propenylation has been reported by taking -allyl benzimidazole as an allylamine congener. This transformation has been observed for the first time, where a tandem process of C-H allylation followed by alkene isomerization delivers a highly stereoselective -propenylated product. Detailed mechanistic studies including the characterization of rhodacycle-intermediates have been conducted to understand the mechanism.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d2cc06048e | DOI Listing |
Publication Analysis
Top Keywords
-allylbenzimidazole strategic
4
strategic surrogate
4
surrogate rh-catalyzed
4
rh-catalyzed stereoselective
4
stereoselective -propenylation
4
-propenylation aryl
4
aryl csp-h
4
csp-h bond
4
bond rh-catalyzed
4
rh-catalyzed csp-h
4
Similar Publications
-Allylbenzimidazole as a strategic surrogate in Rh-catalyzed stereoselective -propenylation of aryl C(sp)-H bond.
Chem Commun (Camb)
December 2022
School of Chemical Sciences, National Institute of Science Education and Research (NISER) Bhubaneswar, Jatni, Odisha 752050, India.
Article Synopsis
- A new Rh-catalyzed method for propenylating C(sp)-H bonds using -allyl benzimidazole has been successfully developed.
- This is the first report of this transformation, showcasing a tandem process that involves C-H allylation followed by alkene isomerization for a highly selective -propenylated product.
- Comprehensive mechanistic studies were carried out, characterizing intermediate rhodacycles to gain insights into the reaction mechanism.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!