Cuboid-like phosphorus-doped metal-organic framework-derived CoSe on carbon cloth as an advanced bifunctional oxygen electrocatalyst for rechargeable zinc-air batteries.

Zinc-air batteries (ZABs) are regarded as attractive devices for electrochemical energy storage and conversion due to their outstanding electrochemical performance, low price, and high safety. However, it remains a challenge to design a stable and efficient bifunctional oxygen catalyst that can accelerate the reaction kinetics and improve the performance of ZABs. Herein, a phosphorus-doped transition metal selenide/carbon composite catalyst derived from metal-organic frameworks (P-CoSe/C@CC) is constructed by a self-supporting carbon cloth structure through a simple solvothermal process with subsequent selenization and phosphatization. The P-CoSe/C@CC exhibits a low overpotential of 303.1 mV at 10 mA cm toward the oxygen evolution reaction and an obvious reduction peak for the oxygen reduction reaction. The abovementioned electrochemical performances for the P-CoSe/C@CC are attributed to the specific architecture, the super-hydrophilic surface, and the P-doping effect. Remarkably, the homemade zinc-air battery based on our P-CoSe/C@CC catalyst shows an expected peak power density of 124.4 mW cm along with excellent cycling stability, confirming its great potential application in ZABs for advanced bifunctional electrocatalysis.