Synergistic Cr(VI) reduction and adsorption of Cu(II), Co(II) and Ni(II) by zerovalent iron-loaded hydroxyapatite.

Multi-metal contaminated soil, such as Cr(VI), Cu(II), and Co(II), still challenge the environmental remediation. In this work, zerovalent iron-loaded hydroxyapatite (ZVI/HAP) was first applied to simultaneously adsorb multi-metal in contaminated soil. During the remediation, the co-existing Cu(II), Ni(II), and Co(II) were adsorbed and precipitated onto ZVI/HAP. This "spontaneous deposition" simultaneously achieved the adsorption of the cationic metals and improved the isoelectric point of ZVI/HAP to 4.83 from 1.59, thus significantly alleviating the electronegativity to enhance the capture and reduction efficiency of Cr(VI). The application of ZVI/HAP resulted in the reduction of more than 99% of total Cr(VI) in contaminated soil, and the almost complete adsorption of water-soluble and DTPA-extractable Cu, Ni and Co within 20 d. Based on the sequential extraction and risk reduction assessment, soil Cr, Cu, Ni, and Co speciation was transformed from an unstable state (exchangeable and carbonate-bound fractions) to a relatively stable state, reducing the risk of heavy metals in contaminated soil significantly. This study developed an efficient strategy for the remediation of multi-metal contaminated soil.