AI Article Synopsis

  • This study explored the collection and analysis of microplastics in the air in Auckland, New Zealand, over nine weeks, utilizing advanced microscopy and pyrolysis-gas chromatography-mass spectrometry (Pyr-GC/MS) to identify various types of airborne microplastics.
  • The findings showed that smaller microplastics were found in higher numbers and emphasized the need for standardized methods when comparing microplastic research.
  • The research identified eight different polymers, with polyethylene, polycarbonate, and PET being the most prevalent, and noted that wind patterns from coastal areas contributed to increased microplastic deposition on urban rooftops.

Article Abstract

This study investigated the atmospheric deposition of microplastics (MPs) in Auckland, New Zealand, from two sampling sites over a 9-week period. The sizes, morphologies, number counts, and mass concentrations of specific polymers were determined for airborne MPs using a combination of a Nile Red-assisted automated fluorescence microscopy technique in series with pyrolysis-gas chromatography-mass spectrometry (Pyr-GC/MS). This enabled a larger number of MPs to be analyzed from each sample compared to traditional spectroscopic techniques. Microplastic number concentrations increased exponentially with decreasing size. The results show the importance of using consistent methodologies and size cutoffs when comparing microplastic data between studies. Eight polymers were quantified in the atmospheric deposition samples, with polyethylene (PE), polycarbonate (PC), and poly(ethylene terephthalate) (PET) being the most commonly observed. The largest MP deposition rates at an urban rooftop correlated with winds originating from the marine environment with speeds between 15 and 20 m s, indicating that airborne MPs in coastal regions may originate from wave-breaking mechanisms. This study represents the first report of using Pyr-GC/MS to determine the chemical compositions and mass concentrations of atmospheric microplastics, along with corresponding data on their sizes, morphologies, and number counts.

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http://dx.doi.org/10.1021/acs.est.2c05850DOI Listing

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