The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 and 460 K by using a discharge flow-electron paramagnetic resonance technique. The rate constants were found to be (298 K) = (7.9 ± 1.3) × 10 cm molecule s with a weak positive temperature dependence, (298-460 K) = (1.04 ± 0.2) × 10 cm molecule s, and (298 K) = (3.0 ± 0.3) × 10 cm molecule s, respectively. The homogeneous nature of these reactions has been experimentally tested.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9706651 | PMC |
| http://dx.doi.org/10.1002/kin.21404 | DOI Listing |
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