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Unique amorphous/crystalline heterophase coupling for an efficient oxygen evolution reaction. | LitMetric

Unique amorphous/crystalline heterophase coupling for an efficient oxygen evolution reaction.

Nanoscale

The School of Chemistry and Chemical Engineering, State Key Laboratory of Power Transmission Equipment & System Security and New Technology, Chongqing University, 174 Shazheng Street, Shapingba District, Chongqing City, 400044, PR China.

Published: December 2022

AI Article Synopsis

Article Abstract

Designing amorphous/crystalline heterophase catalysts is still in the initial stage, and the study of amorphous/crystalline heterophase and carbon-free catalysts has not yet been realized. Herein, we report a unique amorphous/crystalline heterophase catalyst consisting of NiFe alloy nanoparticles (NPs) supported on TiO (NiFe/TiO) for the first time, which is achieved by a heterophase supporting strategy of dual heat treatment. Surprisingly, the amorphous/crystalline heterophase is flexibly composed of amorphous and crystalline phases of alloy NPs and TiO. The heterophase coupling endows the catalyst with a low overpotential (256 mV at 10 mA cm), a small Tafel slope (47 mV dec) and excellent endurance stability (over 100 h) in 1 M KOH electrolyte, which already outperforms commercial RuO (338 mV and 113 mV dec) and exceeds most reported representative carbon-based and titanium-based non-precious metal catalysts. The density functional theory (DFT) calculations and experimental results reveal that the unique amorphous/crystalline heterophase coupling in NiFe/TiO results in electron transfer between the alloy NPs and TiO, allowing more catalytically active sites and faster interfacial electron transfer dynamics. This work provides insights into the synthesis of amorphous/crystalline heterophase catalysts and can be generalized to the heterophase coupling of other transition metal-based electrocatalysts.

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Source
http://dx.doi.org/10.1039/d2nr05167bDOI Listing

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