With regard to the global energy crisis and environmental pollution, ferroelectric thin films with unique polarization behavior have garnered considerable attention for energy storage and electrocaloric refrigeration. Herein, a series of (1 - )BiNaTiO-Ba(ZrTi)O ( = 0.3-0.9; (1 - )BNT-BZT) films were fabricated on Pt(111)/Ti/SiO/Si substrates. Incorporating BZT can tune the polarization behavior and phase transition temperature of BNT. A high recoverable energy density ≈ 82 J cm and optimized efficiency ≈ 81% were realized for the (1 - )BNT-BZT thin film with = 0.7. The thin film exhibits excellent stability in energy storage performance, a wide working frequency range (0.5-20 kHz), a broad operating temperature window (20-200 °C), and reduplicative switching cycles (10 cycles). In addition, the 0.5BNT-0.5BZT film exhibits a desirable electrocaloric effect with a large adiabatic temperature change (Δ ≈ -22.9 K) and isothermal entropy change (Δ ≈ 33.4 J K kg) near room temperature under a moderate applied electric field of 2319 kV cm. These remarkable performances signify that the (1 - )BNT-BZT system is a promising multifunctional electronic material for energy storage and solid-state cooling applications.
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