Two-dimensional holographic structures based on photopolymer compositions with luminescent nanoparticles, such as quantum dots, are promising candidates for multiresponsive luminescence sensors. However, their applicability may suffer from the incompatibility of the components, and hence aggregation of the nanoparticles. We showed that the replacement of an organic shell at the CdSe/ZnS quantum dots' surface with monomer molecules of the photopolymerizable medium achieved full compatibility with the surrounding medium. The effect was demonstrated by luminescence spectroscopy, and steady-state and time-resolved luminescent laser scanning microscopy. We observed the complete spectral independence of local photoluminescence decay, thus proving the absence of even nanoscale aggregation, either in the liquid composition or in the nodes and antinodes of the grating. Therefore, nanostructured luminescent photopolymer gratings with monomer-covered quantum dots can act as hybrid diffractive-luminescent sensor elements.
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http://dx.doi.org/10.3390/ma15228195 | DOI Listing |
Molecules
December 2024
State Key Laboratory of Molecular Engineering of Polymers, Laboratory of Advanced Materials, Shanghai Key Lab of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200438, China.
With the development and improvement of analysis and detection systems, low-toxicity and harmless detection systems have received much attention, especially in the field of food detection. In this paper, a low-toxicity dual-emission molecularly imprinted fluorescence sensor (CdTe QDs@SiO/N-CDs@MIPs) was successfully designed for highly selective recognition and visual detection of tetracycline (TC) in food samples. Specifically, the non-toxic blue-emission N-doped carbon dots (N-CDs) with high luminous performance acted as the response signals to contact TC via the covalent bond between amino and carboxyl groups.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Department of Chemistry and Chemical Technologies, University of Calabria, 87036 Rende, Italy.
We report the design and development of a novel multifunctional nanostructure, RB-AuSiO_HSA-DOX, where tri-modal cancer treatment strategies-photothermal therapy (PTT), photodynamic therapy (PDT), chemotherapy-luminescent properties and targeting are integrated into the same scaffold. It consists of a gold core with optical and thermo-plasmonic properties and is covered by a silica shell entrapping a well-known photosensitizer and luminophore, Rose Bengal (RB). The nanoparticle surface was decorated with Human Serum Albumin (HSA) through a covalent conjugation to confer its targeting abilities and as a carrier of Doxorubicin (DOX), one of the most effective anticancer drugs in clinical chemotherapy.
View Article and Find Full Text PDFACS Nano
January 2025
School of Science and Engineering, Shenzhen Institute of Aggregate Science and Technology, The Chinese University of Hong Kong, Shenzhen (CUHK-Shenzhen), Guangdong 518172, P.R. China.
Helical structures such as right-handed double helix for DNA and left-handed α-helix for proteins in biological systems are inherently chiral. Importantly, chirality at the nanoscopic level plays a vital role in their macroscopic chiral functionalities. In order to mimic the structures and functions of natural chiral nanoarchitectures, a variety of chiral nanostructures obtained from artificial helical polymers are prepared, which can be directly observed by atomic force microscopy (AFM), scanning tunneling microscopy (STM), scanning electron microscopy (SEM), and transmission electron microscopy (TEM).
View Article and Find Full Text PDFJ Food Drug Anal
December 2024
Zhenjiang College, Zhenjiang, 212000, PR China.
Ascorbic acid (AA) is used as a food additive for its antibacterial and antioxidant properties. However, excessive intake of AA is harmful to humans. Therefore, the detection of Fe and AA is generally recognized to be meaningful.
View Article and Find Full Text PDFLuminescence
January 2025
Pharmaceutical Chemistry Department, Faculty of Pharmacy, Misr International University, Cairo, Egypt.
Affordable and eco-friendly green spectrofluorometric (FL) methods can enhance the safety and cost-effectiveness of quality assurance and control in ascorbic acid (ASA) formulations. However, most current techniques for ASA analysis have faced challenges like complexity, delayed response times, low throughput, time-consuming procedures, and requirements for expensive equipment and hazardous chemicals for analyte modification. The study is aimed at producing natural carbon quantum dots (NACQDs) from pumpkin seed peels (PSPs), a natural waste material, using a rapid microwave-assisted method.
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