Purpose: The United States (US) federal government uses health provider shortage areas (HPSAs) to define patient accessibility to primary care physicians. It is unclear whether HPSAs can be applied to eye care providers (ECPs). Our study determined the applicability of federal HPSA designations to ECP availability in the US.
Design: Cross-sectional study.
Participants: US general population and ophthalmologists/optometrists in the Medicare database.
Methods: The primary care HPSA score, visual impairment prevalence, and ECP location were determined for each census tract or county using data from the US Department of Health and Human Services, the Centers for Disease Control and Prevention, and Centers for Medicare and Medicaid Services.
Main Outcome Measures: Association of HPSA with vision loss and ECP density was examined. The 2-step floating catchment area approach was used to newly define eye care shortage areas (patient accessibility score [PAS], higher being worse accessibility) for every county in the US, by weighting the 2-step FCA scores by prevalence of vision loss and ECP density. Multivariable logistic regression was used to identify sociodemographic variables associated with areas of ECP shortage.
Results: Among 72 735 census tracts included, statistically significant but weak correlations of HPSA score with visual impairment (VI) (r = 0.38; P < 0.0001) and ECP density per county population (r = -0.18; P < 0.0001) were found. Only 54.0% of census tracts with < 25th percentile ECP density per county were HPSAs (P < 0.0001). Of census tracts > than 75th percentile for VI only 58.0% were HPSAs (P < 0.0001). Multivariable regression found a higher odds of ECP PAS ≥ 75th percentile (worse accessibility) in rural counties (adjusted odds ratio [aOR], 2.47; 95% confidence interval [CI], 1.93-3.67; P < 0.001) and counties with a greater prevalence of residents with less than a high school education (aOR, 1.21; 95% CI, 1.19-1.25; P < 0.001), residents ≥ 65 years of age (aOR, 1.10; 95% CI, 1.07-1.13; P < 0.001), and uninsured residents (aOR, 1.04; 95% CI, 1.01-1.06; P < 0.001). Counties with a greater proportion of men (aOR, 0.93; 95% CI, 0.89-0.967; P < 0.001) or White residents (aOR, 0.99; 95% CI, 0.98-0.99) had a lower odds of ECP PAS ≥ 75th percentile.
Conclusions: Current HPSAs only weakly correlate with ECP supply. We propose a new approach to identify counties with high need but limited access to eye care.
Financial Disclosure(s): Proprietary or commercial disclosure may be found after the references.
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http://dx.doi.org/10.1016/j.ophtha.2022.11.017 | DOI Listing |
J Mol Model
August 2024
Chemistry Department, CINVESTAV, Av. Instituto Politecnico Nacional 2508, Col. San Pedro Zacatenco, Del. Gustavo A. Madero, Mexico City, C.P. 07360, Mexico.
Context: Analytic exchange-correlation kernel formulations are of the outermost importance for density functional theory (DFT) perturbation calculations. In this paper, the working equation for the exchange-correlation kernel of the generalized gradient approximation (GGA) for perturbation dependent auxiliary functions is derived and discussed in the framework of auxiliary density functional theory (ADFT). The presented new formulation is extended to the unrestricted approach, too.
View Article and Find Full Text PDFJ Phys Chem A
August 2024
Department of Chemistry and Biochemistry, Butler University, Indianapolis, Indiana 46208, United States.
The reliable and accurate prediction of chemical properties is a key goal in quantum chemistry. Transition-metal-containing complexes can often pose difficulties to quantum mechanical methods for multiple reasons, including many electron configurations contributing to the overall electronic description of the system and the large number of electrons significantly increasing the amount of computational resources required. Often, multiconfigurational electronic structure methods are employed for such systems, and the cost of these calculations can be reduced by the use of an effective core potential (ECP).
View Article and Find Full Text PDFDalton Trans
July 2024
Department of Chemistry, Faculty of Science, University of Helsinki, P. O. Box 55 (A. I. Virtasen aukio 1), FIN-00014, Helsinki, Finland.
Nuclear magnetic resonance (NMR) chemical shifts and the magnetically induced current density (MICD) susceptibility of four osmium containing molecules have been calculated at the density functional theory (DFT) level using three relativistic levels of theory. The calculations were performed at the quasi-relativistic level using an effective core potential (ECP) for Os, at the all-electron scalar exact two-component (X2C) relativistic level, and at the relativistic X2C level including spin-orbit coupling (SO-X2C). In earlier studies, the osmapentalene (1) and the osmapentalynes (2 and 3) were considered Craig-type Möbius aromatic and it was suggested that the analogous osmium compound (4) is Craig-type Möbius antiaromatic.
View Article and Find Full Text PDFPhys Chem Chem Phys
June 2024
Department of Physics, Rheinland-Pfälzische Technische Universität Kaiserslautern (RPTU) Kaiserslautern-Landau, P.O. Box 3049, 67653 Kaiserslautern, Germany.
The accomplishment of long-distance spin transfer scenarios between several magnetic centers is a big challenge for building and supporting spin-logic units for developing future all-optical magnetic unit operations. Using high-level quantum chemistry theory CCSD and EOM-CCSD, we systematically study the ultrafast laser-induced spin-dynamics process on a carbon-based material, to which four magnetic centers are attached. We show that the CCSD method with the 6-31G basis set calculation is sensitive to the C-Ni bond length.
View Article and Find Full Text PDFJ Mol Model
May 2024
Graduate Program in Chemistry, State University of Piaui, Teresina, PI, Brazil.
Context: Bismuth complexes with dithiocarbamate ligands have attracted attention because of their biological applications, such as antimicrobial, antileishmanial, and anticancer properties. These complexes have high cytotoxic activity against cancer cells, being more active than the standard drugs cisplatin, doxorubicin, and tamoxifen. In the present study, we investigated the ability of some DFT methods to reproduce the geometries and NMR spectra of the Bi(III) dithiocarbamate complexes, selected based on their proven antitumor activity.
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