The isomerization of dimethyl 2,3-dibromofumarate in chloroform solutions was investigated by the combination of nuclear magnetic resonance (NMR) and density functional theory (DFT) calculations. The bromination of dimethyl acetylenedicarboxylate leading to dimethyl 2,3-dibromofumarate produces the isomer initially, which however converts into the more stable isomer. The conversion from to is spontaneous and greatly accelerated by light.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9661881 | PMC |
| http://dx.doi.org/10.1039/d2ra05996g | DOI Listing |
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