This paper proposes a new flexible discrete triplet Lindley model that is constructed from the balanced discretization principle of the extended Lindley distribution. This model has several appealing statistical properties in terms of providing exact and closed form moment expressions and handling all forms of dispersion. Due to these, this paper explores further the usage of the discrete triplet Lindley as an innovation distribution in the simple integer-valued autoregressive process (INAR(1)). This subsequently allows for the modeling of count time series observations. In this context, a novel INAR(1) process is developed under mixed Binomial and the Pegram thinning operators. The model parameters of the INAR(1) process are estimated using the conditional maximum likelihood and Yule-Walker approaches. Some Monte Carlo simulation experiments are executed to assess the consistency of the estimators under the two estimation approaches. Interestingly, the proposed INAR(1) process is applied to analyze the COVID-19 cases and death series of different countries where it yields reliable parameter estimates and suitable forecasts via the modified Sieve bootstrap technique. On the other side, the new INAR(1) with discrete triplet Lindley innovations competes comfortably with other established INAR(1)s in the literature.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1515/ijb-2022-0001 | DOI Listing |
Mem Cognit
December 2024
Department of Psychology, City St George's, University of London, Northampton Square, London, EC1V 0HB, UK.
Statistical learning is a mechanism for detecting associations among co-occurring elements in many domains and species. A key controversy is whether it leads to memory for discrete chunks composed of these associated elements, or merely to pairwise associations among elements. Critical evidence for the mere-association view comes from the "phantom-word" phenomenon, where learners recognize statistically coherent but unattested items better than actually presented items with weaker internal associations, suggesting that they prioritize pairwise associations over memories for discrete units.
View Article and Find Full Text PDFEntropy (Basel)
September 2024
Computational Science Lab, Informatics Institute, University of Amsterdam, 1098 Amsterdam, The Netherlands.
Higher-order relationships are a central concept in the science of complex systems. A popular method of attempting to estimate the higher-order relationships of synergy and redundancy from data is through the O-information. It is an information-theoretic measure composed of Shannon entropy terms that quantifies the balance between redundancy and synergy in a system.
View Article and Find Full Text PDFPhys Chem Chem Phys
September 2024
Theoretische Chemie, Physikalisch-Chemisches Institut, Universität Heidelberg, INF 229, D-69120 Heidelberg, Germany.
A quantal description of nuclear motion using coupled fifteen-state potential energy and spin-orbit coupling surfaces for studying the photodissociation of CHOO to HCO(XA) + OD and HCO(XA) + OP channels is presented. For the evaluation of surfaces, multireference electronic wave functions are employed. For the fully quantal description of the nuclear motion, we diabatize the PESs of the two and four lowest excited singlet and triplet states, respectively, within the three sets of vibronically coupled states, (BA', CA'), (aA', bA') and (aA'', bA''), employing the diabatization by ansatz method.
View Article and Find Full Text PDFInorg Chem
September 2024
Institute of Chemistry, St Petersburg University, Universitetskii pr. 26, St. Petersburg 198504, Russia.
Two series of heteroleptic monoalkynylphosphonium Pt(II) complexes decorated with 2,2':6',2''-terpyridine (, series) and 6-phenyl-2,2'-bipyridine (, series) ligands, were prepared and characterized by spectroscopic methods. The complexes obtained exhibit triplet emission in solution, and the characteristics inside the series depend on the nature of the alkynylphosphonium ligand. The description of electronic transitions responsible for energy absorption and emission in discrete Pt(II) complexes was made on the basis of a detailed analysis of the results of DFT calculations, and has shown to involve MLCT, ILCT, and LLCT transitions.
View Article and Find Full Text PDFPhys Chem Chem Phys
July 2024
Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Shaanxi 710127, China.
Directly fixing dinitrogen into value-added organics is one of the core issues, and yet a long-standing challenge, in chemical synthesis. In earlier discrete studies, direct amination of benzene with N has been achieved non-thermal plasma-liquid reaction. Nonetheless, the reaction mechanism thereof remains elusive and the amination product was non-selective primarily including aniline and diphenylamine.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!