Inorganic halide perovskites have attracted interest due to their high efficiency and low cost. Considering the uncertainty of experimental measurements, it was important to predict the upper limit of carrier mobility. In this study, theBoltzmann transport equation, including all electron-phonon interactions, was used to accurately predict the mobilities of CsPbI, CsSnI, CsPbBr, and CsSnBr. Using the iterative Boltzmann transport equation (IBTE), the calculated mobility for CsPbIis= 512/= 379 cm V s, and Sn-based perovskite exhibited high hole mobility. The longitudinal optical phonons associated with the stretching between halogen anions and divalent metal cations were revealed to be the dominant scattering source for the carriers. Furthermore, the effect of biaxial strain on mobility was investigated. We observed that biaxial compressive strain could improve the mobility of CsPbIand CsPbBr. Surprisingly, under a compressive strain of-2%, the mobilities of CsPbIusing IBTE approach were improved to= 1176/= 936 cm V s. It was revealed that the compressive strain could decrease the effective mass of CsPbIand CsPbBr.
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http://dx.doi.org/10.1088/1361-648X/aca3eb | DOI Listing |
Phys Chem Chem Phys
January 2025
Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences, Suzhou 215123, China.
In the study of GaN/AlGaN heterostructure thermal transport, the interference of strain on carriers cannot be ignored. Although existing research has mainly focused on the intrinsic electronic and phonon behavior of the materials, there is a lack of studies on the transport characteristics of the electron-phonon coupling in heterostructures under strain control. This research comprehensively applies first-principles calculations and the Boltzmann transport equation simulation method to deeply analyze the thermal transport mechanism of the GaN/AlGaN heterojunction considering in-plane strain, with particular attention to the regulatory role of electron-phonon coupling on thermal transport.
View Article and Find Full Text PDFAcad Emerg Med
January 2025
Department of Emergency and Critical Care Medicine, Saitama Medical Center, Jichi Medical University, Saitama, Japan.
Background: This study aimed to clarify the appropriate timing for epinephrine administration in adults with out-of-hospital cardiac arrest (OHCA), particularly those cases with nonshockable rhythms, by addressing resuscitation time bias.
Methods: We performed a retrospective observational study utilizing a multicenter OHCA registry involving 95 hospitals in Japan between June 2014 and December 2020. We included patients with OHCA and nonshockable rhythms who received epinephrine during resuscitation.
Phys Chem Chem Phys
January 2025
Faculty of Information Science and Technology, Hokkaido University, Sapporo 060-0814, Japan.
To realize the optical transfer of electron spin information, developing a semiconductor layer for efficient transport of spin-polarized electrons to the active layers is necessary. In this study, electron spin transport from a GaAs/AlGaAs superlattice (SL) barrier to InGaAs quantum dots (QDs) is investigated at room temperature through a combination of time-resolved photoluminescence and rate equation analysis, separating the two transport processes from the GaAs layer around the QDs and SL barrier. The electron transport time in the SL increases for a thicker quantum well (QW) of SL due to the weaker wavefunction overlap between adjacent QWs.
View Article and Find Full Text PDFSci Total Environ
January 2025
University of São Paulo, Luiz de Queiroz College of Agriculture, Department of Soil Science, Brazil.
Phosphorus (P) movement in soils is influenced by flow velocities, diffusion rates, and several soil characteristics and properties. In acidic soils, P is tightly bound to soil particles, reducing its availability to plants. Organomineral fertilizers combine organic matter with mineral nutrients, enhancing P fertilization efficiency, and reducing environmental impacts.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Section on Molecular Transport, Eunice Kennedy Shriver National Institute of Child Health and Human Development, National Institutes of Health, Bethesda, Maryland 20892, USA.
One of the most subtle steps in the single-molecule approach to the flux through the membrane channel, which uses the one-dimensional Smoluchowski equation, is to describe the molecule's "behavior" at the contacts between the channel openings and the bulk. Earlier, to handle this issue, we introduced the so-called "radiation boundary conditions" that account for the interplay between the two types of trajectories of the molecules starting at the openings, specifically, the ones that eventually return to the channel and the ones that escape to infinity. The latter trajectories represent the true translocation events on the condition that initially the molecule entered the channel from the opposite side.
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