The planar title compound 4,5-dimethyl-1,3-dioxol-2-one, CHO, , crystallizes with its mol-ecular axis coincident with a crystallographic mirror plane in space group 2/. In the plane defined by the axis and an face diagonal, anti-parallel linear strands of , formed by simple translation, associate to form sheets with close H⋯H and O⋯O inter-molecular contacts. Between the sheets, parallel strands of place the carbonyl O atom near the five-membered ring centroid of a neighboring mol-ecule with close O⋯O and O⋯C contacts.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9638974 | PMC |
http://dx.doi.org/10.1107/S2056989022009239 | DOI Listing |
J Org Chem
March 2025
Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, and School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241002, P. R. China.
Tether-directed electrosynthesis of [60]fullerene derivatives fused with 5-membered azacycle and 13-membered carbocycle, that is, bicyclic 1,4,9,12- and 1,2,4,15-adducts, has been achieved unexpectedly for the first time. The novel bicyclic [60]fullerene derivatives are obtained by the electrochemical reduction of [60]fullerene-fused indolines or lactams and subsequent regioselective cyclization with 2,2″-bis(bromomethyl)-1,1':3',1″-terphenyl. The product structures have been characterized by spectroscopic data and single-crystal X-ray analysis.
View Article and Find Full Text PDFJ Mol Biol
March 2025
Department of Chemistry and Biochemistry University of California, Los Angeles Los Angeles, CA 90095-1569.
I am Distinguished Professor in the Chemistry and Biochemistry Department at University of California, Los Angeles, where I was hired in 1985 as the first female assistant professor in the department. I received my PhD from University of California, San Diego, under the guidance of Professor David Kearns, where I used NMR spectroscopy to study drug binding to random sequence DNA and published the first two-dimensional NMR spectra of short synthetic DNA duplexes. From 1982-1985 I was a Damon Runyon-Walter Winchell Postdoctoral fellow in the Professor Alexander Rich laboratory, where I investigated structures of Z-DNA by NMR.
View Article and Find Full Text PDFInt J Pharm
March 2025
The Casali Center for Applied Chemistry, The Institute of Chemistry, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Jerusalem 9190401, Israel. Electronic address:
The present study introduces a novel formulation approach for utilizing Lyotropic Liquid Crystals (LLCs) as sustained oral delivery systems. For this purpose, we have developed a novel bottom-up fabrication process that enables the LLC beads to be formulated with precise control over their diameter by pre-determining their surface area. By directly controlling the effective diffusional interfacial surface of the LLCs, their release rate from the LLC beads can be determined.
View Article and Find Full Text PDFEnviron Res
March 2025
Hangzhou Yanqu Information Technology Co., Ltd., Y2,2nd Floor, Building 2, Xixi Legu Creative Pioneering Park, No. 712 Wen'er West Road, Xihu District, Hangzhou City, 310003, P.R.O.C.
In this study, a ternary hydrotalcite of Mg/Al/Fe/SDBS-LDHs was synthesized via a hydrothermal method, utilizing sodium dodecyl benzene sulfonate (SDBS) as a modifier. The prepared Mg/Al/Fe/SDBS-LDHs were characterized using FT-IR, SEM, XRD, TG, BET, ESR and XPS techniques. The CV removal process was monitored and analyzed using UV-vis spectroscopy, DFT and LC-MS methods.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
Yaoshan laboratory, Pingdingshan University, Pingdingshan, Henan 467000, P.R. China.
The development of superior non-noble-metal-based oxygen evolution reaction (OER) electrocatalysts is essential for large-scale hydrogen production. In this study, an integrated porous nanosheet NiP-NiP heterostructures were designed as an excellent OER electrocatalyst. The synthesized heterostructures demonstrated notable activity, achieving a small overpotential of 260 mV to sustain a typical 10 mA cm current density, along with exceptional durability over 2000 CV cycles.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!