In this study, the contents of heavy metals (HMs) such as Al, Cd, Co, Cr, Cu Fe, Mn, Ni, Pb and Zn in soil samples collected from 403 sampling locations of the agricultural lands of Adıyaman Province (Türkiye) were determined by Inductively Coupled Plasma‒Optical Emission Spectrometry (ICP‒OES). The mean concentrations of Al, Cd, Co Cr, Cu Fe, Mn, Ni, Pb and Zn HMs were detected 28,986, 3.60, 15, 127, 52.67, 45,830, 817, 62.40, 10.75 and 66.25 mg kg, respectively. These results showed that the average concentrations of Cd, Cr, Cu, Fe, Mn and Ni exceeded the Upper continental crust average. To determine and to evaluate the contamination status and distribution of HMs in agricultural soils, metal pollution parameters such as enrichment factor (EF), geoaccumulation index (I), contamination factor (Cf), pollution load index, potential ecological risk factor (Er), and potential ecological risk index (RI) were used. Factor analyses (FA) and principal component analyses (PCA) indicated that Cd, Cr and Ni levels were influenced by anthropogenic sources, Fe by both lithological and anthropogenic sources, and other HMs by lithogenic origins. For both children and adults, the hazard index (HI) and total hazard index (THI) values of HMs were < 1, suggesting that non-carcinogenic health risks to residents through ingestion, inhalation pathways, and dermal contact were currently absent. In addition, the cumulative carcinogenic risk (CCR) results were within the acceptable risk range (10 to 10). The results showed that children were more sensitive to the non-carcinogenic and carcinogenic effects of HMs.

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http://dx.doi.org/10.1007/s10653-022-01423-5DOI Listing

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