Enhanced methane production in anaerobic co-digestion systems with modified black phosphorus.

Black phosphorus (BP) and BP modified by hydrogen peroxide (MBP) were used as accelerants to enhance CH production and CO reduction in microbial electrolysis cells (MECs) coupled with anaerobic co-digestion systems (MEC-AcoD). The MEC-AcoD group with a voltage of 0.6 V and 0.03 wt.% of MBP accelerant (MECMBP) had the largest CH yield (242.1 mL/g VS) and the smallest carbon dioxide yield (97.6 mL/g VS) compared with the control group (141.2 mL/g VS, 146.9 mL/g VS). The digestates that used MECMBP exhibited superior thermal stability (46.2 %) and total nutrient contents (44.5 g/kg). These improvements may be attributed to the superior electron exchange capacity and physicochemical properties of MBP. Herein, we propose a strategy to understand enhanced CH production and CO reduction in anaerobic co-digestion and MEC-AcoD systems using MBP accelerants. Notably, combining MBP and MEC could effectively promote anaerobic co-digestion performance.