In air and railway transportation, corrosion and wear lead to the rapid failure of equipment. Epoxy (EP)-based coatings are widely used in research on the anti-corrosion of organic coatings, but their application as materials for wear resistance is limited due to their non-abrasive properties. In this study, a novel high-performance epoxy-based composite coating was developed through the self-assembly of silicon carbide (SiC) and graphene oxide (GO) and the tuning of the interfacial structure with epoxy resin. The coatings were comprehensively characterized, including their electrochemical behavior, a salt spray test, and friction and wear experiments, and the optimal addition ratio of SiC-G@GO (SiC-G@GO was prepared by the self-assembly of γ-(2,3-epoxypropoxy) propytrimethoxysilane (KH560)-modified SiC (SiC-G) on the surface of GO sheets) in the epoxy coatings was explored. Benefiting from the labyrinth effect and their rolling-friction-like microstructure, the 1 wt% SiC-G@GO/EP coating exhibits excellent wear and corrosion resistance. Compared with pure epoxy resin, the 1 wt% SiC-G@GO/EP coating increased by 4 orders of magnitude after 10 days of immersion. The average friction coefficient was 41.5% lower than that of the pure EP coating, and the wear rate was 56.6% lower. This research has positive implications for the development and application of anti-corrosion and wear-resistant organic coatings.
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http://dx.doi.org/10.3390/polym14214704 | DOI Listing |
Nanoscale
January 2025
Pro2TecS - Chemical Product and Process Technology Research Center. Department of Chemical Engineering and Materials Science. Universidad de Huelva. ETSI, Campus de "El Carmen", 21071 Huelva, Spain.
This study explores the preparation of lubricating oleo-dispersions using electrospun nanofibrous mats made from low-sulfonate lignin (LSL) and polycaprolactone (PCL). The rheological and tribological properties of the oleo-dispersions were significantly modulated for the first time through the exploration of LSL/PCL ratio and electrospinning conditions such as applied voltage, distance between the tip and collector, flow rate, ambient humidity, and collector configuration. Adequate uniform ultrathin fibers and Small-amplitude oscillatory shear (SAOS) functions of the oleo-dispersions, with storage modulus values ranging from 10 to 10 Pa at 25 °C, were obtained with a flow rate of 0.
View Article and Find Full Text PDFACS Omega
January 2025
Engineering Research Center for Waste Oil Recovery Technology and Equipment, Ministry of Education, Chongqing Technology and Business University, Chongqing 400067, P. R. China.
Numerous oil-water mixtures produced through industrial production processes and daily activities pollute the ecological environment and pose risks to human health. The development of materials with high oil-water mixture separation efficiency can promote the recycling of oil and water resources and effectively prevent environmental pollution caused by their direct discharge. Most of the current oil-water separation materials consist of foam, aerogel, and other porous materials.
View Article and Find Full Text PDFJ Psychopharmacol
January 2025
Translational and Clinical Research Institute, Newcastle University, Newcastle upon Tyne, UK.
Background: Options for 'treatment-resistant bipolar depression' (TRBD) are limited. Two small, short-term, trials of pramipexole suggest it might be an option.
Aims: To evaluate the clinical effectiveness and safety of pramipexole in the management of TRBD.
J Colloid Interface Sci
January 2025
School of Mechanical Engineering, Jiangsu University, Zhenjiang 212013 China.
Superhydrophobic surfaces have been demonstrated to exhibit excellent anti-icing effects, but they are susceptible to the loss of ice repellency as a result of external impacts. This paper proposes a novel bionic armour structure that combines an armour structure with an arrowroot bionic structure. A composite method combining laser etching and chemical modification was employed to achieve superhydrophobicity on the surface of the aluminium alloy.
View Article and Find Full Text PDFMar Pollut Bull
January 2025
Department of Materials Science and Engineering, Dalian Maritime University, Dalian 116026, PR China; Dalian Key Laboratory of Internal Combustion Engine Tribology and Reliability Engineering, Dalian 116026, PR China. Electronic address:
As a global challenge, marine biofouling is causing serious economic losses and adverse ecological impacts. In recent years, a variety of promising and environmentally friendly anti-fouling strategies have emerged, among which the excellent anti-fouling performance of bionic autocrine coatings has been recognized. However, bionic autocrine coatings still suffer from uncontrollable secretion behavior, poor mechanical stability, and poor abrasion resistance.
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