Corrosion of steel bars is of great significance for safety and service life of reinforced concrete structures. This work develops a prediction method for steel corrosion mass loss rate before the crack of concrete structure based on a spiral distributed fiber optic sensor. Reinforced concrete sample instrumented with a spiral distributed fiber optic sensor were prepared. The mathematic relationship between the corrosion mass loss rate of steel bar and the spiral distributed strain is theoretically derived. Meanwhile, numerical analysis by MATLAB shows that these parameters such as the protective layer thickness, corrosion mass loss rate, bar diameter, corrosion expansion coefficient have a remarkable influence on spiral distributed strain. Additionally, electrical accelerated corrosion experiment was performed on the reinforced concrete specimens. The helix strain along the distributed sensor was used to evaluate the corrosion mass loss of steel bar. Further, the influencing factors on the corrosion sensitivity are illustrated here and the corrosion mass loss rate before concrete crack is also quantified. This research provides insights into the corrosion deteriorate mechanism.
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http://dx.doi.org/10.3390/mi13111868 | DOI Listing |
Metabolites
December 2024
Leicester School of Pharmacy, De Montfort University, Leicester LE1 9BH, UK.
Since the biological activities and toxicities of 'foreign' and/or excess levels of metal ions are predominantly determined by their precise molecular nature, here we have employed high-resolution H NMR analysis to explore the 'speciation' of paramagnetic Ni(II) ions in human saliva, a potentially rich source of biomolecular Ni(II)-complexants/chelators. These studies are of relevance to the corrosion of nickel-containing metal alloy dental prostheses (NiC-MADPs) in addition to the dietary or adverse toxicological intake of Ni(II) ions by humans. Unstimulated whole-mouth human saliva samples were obtained from n = 12 pre-fasted (≥8 h) healthy participants, and clear whole-mouth salivary supernatants (WMSSs) were obtained from these via centrifugation.
View Article and Find Full Text PDFEnviron Res
January 2025
School of Chemistry and Environmental Engineering, Hubei Minzu University, 39 College Road, Enshi, 445000, China. Electronic address:
Recovery of phosphate from swine wastewater is significant for alleviating eutrophication in aquatic ecosystems and addressing the increasing scarcity of phosphorus resources. In this study, a method for phosphate recovery from swine wastewater using corn carbon as an additive and non-dynamic magnesium metal self-corrosion was studied. The effects of reaction time, C:Mg mass ratio, stirring rate, and aeration rate on phosphate recovery were discussed, and eight experimental models were explored.
View Article and Find Full Text PDFUltrason Sonochem
January 2025
Jiangsu Key Laboratory for Advanced Metallic Materials, School of Materials Science and Engineering, Southeast University, Nanjing 211189, China.
In this study, the cavitation erosion (CE) behavior of wire-arc directed energy deposition (DED) nickel-aluminum bronze (NAB) alloys is compared with that of cast alloys, and the synergistic effect between corrosion and CE is investigated. The CE resistance of the wire-arc DED NAB alloy is better than that of the cast alloys. The CE of NAB alloys preferentially occurs at the boundaries of the α-Cu and residual β phases, and in the matrix around the κ phase.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft, The Netherlands.
Chromium-based functional coatings (CFCs) are widely recognized for their outstanding wear and corrosion resistance across diverse industrial sectors. However, despite advancements in deposition techniques and microstructural enhancements, many contemporary CFCs remain vulnerable to degradation in highly corrosive environments. For the first time, this research delivers a thorough characterization of the corrosion resistance of advanced CFCs, focusing on the performance of a 5 μm thin dense chromium (TDC) coating.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Robotics Engineering, Hanyang University, 55 Hanyangdaehak-ro, Ansan, Gyeonggi-do 15588, Republic of Korea.
This study investigates the corrosion inhibition effects of eco-friendly conifer cone extract (CCE) on steel rebars embedded in cement mortar exposed to 3.5% NaCl under alternate wet/dry cycles. CCE concentrations of 0, 0.
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