The effect of the composition of liquid electrolytes in the bulk and at the interface with the LiFePO cathode on the operation of a solid-state lithium battery with a nanocomposite polymer gel electrolyte based on polyethylene glycol diacrylate and SiO was studied. The self-diffusion coefficients on the 7Li, 1H, and 19F nuclei in electrolytes based on LiBF and LiTFSI salts in solvents (gamma-butyrolactone, dioxolane, dimethoxyethane) were measured by nuclear magnetic resonance (NMR) with a magnetic field gradient. Four compositions of the complex electrolyte system were studied by high-resolution NMR. The experimentally obtained H chemical shifts are compared with those theoretically calculated by quantum chemical modeling. This made it possible to suggest the solvate shell compositions that facilitate the rapid transfer of the Li cation at the nanocomposite electrolyte/LiFePO interface and ensure the stable operation of a solid-state lithium battery.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9694555 | PMC |
| http://dx.doi.org/10.3390/membranes12111111 | DOI Listing |
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