Novel Antireflection Coatings Obtained by Low-Temperature Annealing in the Presence of Tetrabutylammonium Bromide and Gold Nanoparticles.

In this work, nanoporous antireflective coatings on silicate glass were obtained from silicon dioxide sol compositions by the sol-gel method in the presence of quaternary ammonium salt (tetrabutylammonium bromide) at different annealing temperatures (200-250 °C). Varying the salt concentration from 3 to 5 wt.%, we achieved the transmittance of the coatings of about 97% at 250 °C in comparison with 91% for clean glass in the wavelength range from 400 to 1100 nm. The addition of gold nanoparticles to the composition containing 5 wt.% tetrabutylammonium bromide allowed us to decrease the annealing temperature to 200 °C, preserving the transmittance at the level of 96.5%. For this case, the optimal concentration of gold nanoparticles is determined (2.6 × 10 mol/mL). According to the SEM analysis, the obtained antireflective coatings contain pores with a minimum area size up to 4 nm.