The purpose of this research is to discuss the preparation, characterization, and characteristics of lithium disilicate-fluorcanasite (LF) glass-ceramics in order to develop new dental glass-ceramics. A typical melt quenching method was used to produce the lithium disilicate (LD) and fluorcanasite (FC) types of glass. Following that, the LD and FC glass frits were combined and remelted in the following LD:FC ratios of 100:0, 0:100, 75:25, and 50:50 wt%, represented by S1, S2, S3, and S4, respectively. Based on the thermal analysis data, the glass-ceramic samples were fabricated through the heat treatment method. XRD and SEM were used to characterize the phase formation and microstructures of the prepared glass-ceramics. Archimedes' principle, three-point bending, and chemical solubility tests were used to determine density, flexural strength, and chemical solubility, respectively. The elastic modulus and fracture toughness of the selected samples were also evaluated using a Vickers hardness test. It was found that the S3 glass-ceramic sample (S3-789) has a longer LD crystalline phase than that of the S4 glass-ceramic sample (S4-788), resulting in a higher density and hardness. Furthermore, the S3-789 sample had by far the greatest Vickers hardness, elastic modulus, fracture toughness, and flexural strength, so it was chosen for future study to assess its bioactivity in SBF due to its superior mechanical properties and good machinability. The SBF bioactivity test validated the S3-789 sample's high bioactive performance. As a result, the S3-789 sample may be a good option for use as a novel material in dental applications.
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http://dx.doi.org/10.1016/j.jmbbm.2022.105548 | DOI Listing |
Am J Clin Dermatol
January 2025
Dr. Phillip Frost Department of Dermatology and Cutaneous Surgery, University of Miami Miller School of Medicine, Miami, FL, 33136, USA.
Pityriasis rosea (PR) is a prevalent dermatological condition characterized by a distinctive herald patch, followed by secondary eruptions, often forming a "Christmas tree" pattern on the trunk. Despite its recognizable clinical presentation, the etiology of PR remains uncertain, with hypotheses pointing to both infectious and noninfectious origins. Human herpesviruses (HHV) 6 and 7 have been implicated, with evidence suggesting viral reactivation as a potential trigger.
View Article and Find Full Text PDFJ Fluoresc
January 2025
Department of Chemistry, The University of Burdwan, Golapbag, Burdwan, 713104, India.
Nitrogen doped Carbon Quantum Dots (NCQDs) have been synthesized using most economical and easiest hydrothermal process. Here, N-phenyl orthophenylenediamine and citric acid were utilised as a source of nitrogen and carbon for the preparation of NCQDs. The synthesized NCQDs were characterized using experimental techniques like UV - Vis absorption, FT-IR, transmission electron microscopy (TEM), X-ray Diffraction (XRD), EDX, dynamic light scattering (DLS), fluorimeter and time resolved fluorescence spectroscopy.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Institute of Materials Research and Engineering, Sensor and Flexible Electronics, 2 Fusionopolis Way, 138634, SINGAPORE.
Radical covalent organic frameworks (RCOFs) have demonstrated significant potential in redox catalysis and energy conversion applications. However, the synthesis of stable RCOFs with well-defined neutral carbon radical centers is challenging due to the inherent radical instability, limited synthetic methods and characterization difficulties. Building upon the understanding of stable carbon radicals and structural modulations for preparing crystalline COFs, herein we report the synthesis of a crystalline carbon-centered RCOF through a facile post-oxidation process.
View Article and Find Full Text PDFBiomacromolecules
January 2025
Department of Materials Engineering, Indian Institute of Science, C. V. Raman Avenue, Bangalore 560012, India.
Emerging techniques of additive manufacturing, such as vat-based three-dimensional (3D) bioprinting, offer novel routes to prepare personalized scaffolds of complex geometries. However, there is a need to develop bioinks suitable for clinical translation. This study explored the potential of bacterial-sourced methacrylate levan (LeMA) as a bioink for the digital light processing (DLP) 3D bioprinting of bone tissue scaffolds.
View Article and Find Full Text PDFJ Microsc
January 2025
Department of Mechanical, Materials and Aerospace Engineering, University of Liverpool, Liverpool, UK.
Electron backscatter diffraction (EBSD) has developed over the last few decades into a valuable crystallographic characterisation method for a wide range of sample types. Despite these advances, issues such as the complexity of sample preparation, relatively slow acquisition, and damage in beam-sensitive samples, still limit the quantity and quality of interpretable data that can be obtained. To mitigate these issues, here we propose a method based on the subsampling of probe positions and subsequent reconstruction of an incomplete data set.
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