AI Article Synopsis
- - To address the chemical instability of boron due to its lack of electrons, two types of dative π bonds are suggested.
- - These bonds help to stabilize boron atoms in the creation of boron-based clusters, which have hypercoordinate centers.
- - The goal is to develop more stable compounds that can be synthesized effectively in a solid, condensed phase.
Article Abstract
To eliminate the chemical instability caused by the electron-deficiency of boron, two types of usual dative π bonds are recommended for compensating boron atoms in the computational design of boron-based clusters having hypercoordinate centres, which can lead to unusually stable targets for synthesis in the condensed phase.
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| http://dx.doi.org/10.1039/d2cc05654b | DOI Listing |
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