The HETPYNE (HETeroleptic Phenanthroline and alkYNE metal) and DABCO·(zinc porphyrin) interactions were used to assemble the four-component nanorotor ROT-1 that exhibited a highly dynamic alkyne → copper(I) dissociation ( = 240 kHz) at 298 K. Quantitative click reaction transformed ROT-1 into the new rotor ROT-2 ( = 77 kHz) with a triazole → copper(I) linkage thus opening perspectives for bioorthogonal click strategies to biohybrid machinery.
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| http://dx.doi.org/10.1039/d2cc04497h | DOI Listing |
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