Bis(isonicotinamide-κ)silver(I) tri-fluoro-methane-sulfonate aceto-nitrile disolvate.

The central Ag atom of the title salt, [Ag(INAM)](CFSO)·2CHCN, where INAM is isonicotinamide (CHNO), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol-ecular geometry. The formation of polymeric chains {[Ag(INAM)]} , held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating aceto-nitrile mol-ecules that inter-act the silver metal center regium bonds.