In the structure of the title solvated complex, [Pt(CHNS)(CHN)]·CHOS or -[Pt(4-)(qdt)]·dmso (4- = 4-amino-pyridyl, CHN; qdt = quinoxaline-2,3-di-thiol-ate, CHNS; dmso = dimethyl sulfoxide, CHOS) the centrosymmetric complex exhibits Pt-S distances in agreement with other Pt-S bond lengths found in platinum(IV) di-thiol-ene complexes. The qdt ligands have inter-molecular inter-actions with an amine hydrogen atom on a 4- ligand (hydrogen bonding) and have sandwich π-π inter-actions with a neighboring qdt ligand.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462004 | PMC |
| http://dx.doi.org/10.1107/S2414314622001018 | DOI Listing |
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