Highly Efficient Solar Light Driven g-CN@CsWO Heterojunction for the Photodegradation of Colorless Antibiotics.

This study facilitates the synthesis of a graphitic carbon nitride/cesium tungsten oxide (g-CN@CsWO) heterojunction using a solvothermal method. The photocatalytic activities of the prepared samples were examined for the photodegradation of colorless antibiotics, namely tetracycline, enrofloxacin, and ciprofloxacin, as well as cationic and anionic dyes, such as methyl orange, rhodamine B, neutral red, and methylene blue, under full-spectrum solar light. We have purposely selected different kinds of wastewater pollutants of colorless antibiotics and cationic and anionic organic dyes to investigate the potential application of this heterojunction toward different groups of water pollutants. The results revealed that the g-CN@CsWO heterojunction showed an outstanding photocatalytic activity toward all the pollutants with concentrations of 20 ppm each at pH 3 by photocatalytically removing 97% of tetracycline within 3 h, 98% of enrofloxacin within 2 h, 97% of ciprofloxacin within 2.25 h, 98% of methylene blue in 1 h, 99% of rhodamine B within 2 h, 99% of neutral red in 1.25 h, and 95% of methyl orange in 2 h. These findings indicate that the developed photocatalyst possesses excellent photocatalytic properties toward seven different water pollutants that make it a universal photocatalyst. The developed g-CN@CsWO oxide heterojunction also presented a photocatalytic performance better than those of reported solar light active photocatalysts for photodegradation of rhodamine B and tetracycline. The efficient photocatalytic performance of the heterojunction can be ascribed to its extended light-absorbing ability, effective charge separation and fast charge transfer properties, and a high surface area. Moreover, an active species detection experiment also confirmed that superoxide radicals, hydroxyl radicals, and holes played significant roles in the photocatalysis of the organic dyes and tetracycline.