The title compound, [NbClI(HO)]·8THF (THF is tetra-hydro-furan, CHO), comprises an uncharged niobium cluster unit surrounded by THF solvent mol-ecules. The edges of the {Nb} octa-hedron are -coordinated by twelve chlorido ligands. Four in-plane (equatorial plane) aqua ligands and two iodido ligands coordinating above and below the plane are bound at the corners of the {Nb} atomic octa-hedron. O-H⋯O hydrogen bonds are formed between the aqua ligands and the THF solvent mol-ecules; one THF molecule is disordered over two positions with the major component having a site occupancy of 0.64 (2).
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| http://dx.doi.org/10.1107/S2414314622006186 | DOI Listing |
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