AI Article Synopsis
- The compound [Pt(CNS)(NH)] is an octahedral platinum(IV) complex featuring two ammine and two mnt ligands.
- The distances between platinum and both nitrogen (N) and sulfur (S) atoms align with those found in similar platinum(IV) complexes.
- A slight adjustment in the orientation of the mnt ligand allows the nitrogen atoms to form hydrogen bonds with nearby ammine groups.
Article Abstract
The title compound, [Pt(CNS)(NH)], represents an octa-hedral platinum(IV) complex with two ammine and two mnt (mnt = 1,2-di-cyano-ethene-1,2-di-thiol-ato) ligands. The Pt-N and Pt-S distances are consistent with those in other platinum(IV) complexes. As a result of a slight canting of the coordination of the mnt ligand to the platinum(IV) atom, the nitrile nitro-gen atoms are positioned suitably to hydrogen-bond with adjacent ammines.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462246 | PMC |
| http://dx.doi.org/10.1107/S2414314620009803 | DOI Listing |
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