A new triazole-based neutral Rh complex, [Rh(ClBr)(CHN)(CH)], has been synthesized and structurally characterized. The Rh atom has a distorted square-planar coordination environment, formed by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.154). No significant inter-molecular inter-actions other than van der Waals forces are found in the crystal structure. Diffraction data indicated a two-component inversion twin with a ratio of 0.95 (5):0.05 (5).
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462365 | PMC |
| http://dx.doi.org/10.1107/S2414314621008117 | DOI Listing |
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(Chlorido/bromido)[(1,2,5,6-η)-cyclo-octa-1,5-diene](4-isopropyl-1-methyl-1,2,4-triazol-5-yl-idene)rhodium(I).
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August 2021
Department of Chemistry, Millersville University, Millersville, PA 17551, USA.
A new triazole-based neutral Rh complex, [Rh(ClBr)(CHN)(CH)], has been synthesized and structurally characterized. The Rh atom has a distorted square-planar coordination environment, formed by a bidentate cyclo-octa-1,5-diene (COD) ligand, an N-heterocyclic carbene and a halide ligand that shows substitutional disorder (Cl:Br = 0.846:0.
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