In the title salt, [Ni(CHN)(HO)]Cl, the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni atom of the cation situated about a twofold rotation axis. The six-coordinate Ni atom of the cation is connected to four N atoms from two methyl-substituted ethyelenedi-amine ligands and two water mol-ecules in a slightly distorted octa-hedral environment. The five-membered chelate ring is in a slight envelope conformation. The crystal packing features O-H⋯Cl and N-H⋯Cl inter-molecular inter-actions with the Cl ion forming weak bifurcated hydrogen bonds with nearby water mol-ecules and N-H inter-actions, leading to a three-dimensional supra-molecular network structure.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462272 | PMC |
http://dx.doi.org/10.1107/S2414314620011827 | DOI Listing |
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